Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity

Literature Information

Publication Date 2008-09-02
DOI 10.1039/B810935D
Impact Factor 6.222
Authors

James D. Osborne, Michael C. Willis


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Abstract

The pathway for the combination of enones and β-S-substituted aldehydes using Rh-catalysis can be switched between a hydroacylation reaction or a reductive aldol reaction by simple choice of the phosphine ligand; this catalyst controlled switch allows access to new ketone hydroacylation products; useful 1,4-diketone intermediates for the synthesis of N-, S- and O-heterocycles.

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