4-Benzyl-1-(tert-butoxycarbonyl)piperidine-4-carboxylic acid
CAS Number:
170838-87-6
Molecular Formula:
C18H25NO4
Surface-enhanced stereoselectivity in Mukaiyama aldol reactions catalyzed by clay-supported bis(oxazoline)–copper complexes
Literature Information
Publication Date
2008-09-19
DOI
10.1039/B809956A
Impact Factor
6.222
Authors
María J. Fabra, José M. Fraile, Clara I. Herrerías, Fernando J. Lahoz, José A. Mayoral, Ignacio Pérez
View Original
Abstract
Surface effects on a laponite-exchanged bis(oxazoline)–copper complex modify the stereochemical course of the Mukaiyama aldol reaction between 2-(trimethylsilyloxy)furan and α-ketoesters, leading up to 90% ee (dr 86 : 14) becoming the best overall result obtained for this reaction and significantly improving the homogeneous process.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
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