![4-Chloro-3-(trifluoromethyl)-1H-pyrrolo[2,3-b]pyridine structure](https://static.chemtradehub.com/structs/869/869335-75-1-a9d0.webp "4-Chloro-3-(trifluoromethyl)-1H-pyrrolo[2,3-b]pyridine structure")
4-Chloro-3-(trifluoromethyl)-1H-pyrrolo[2,3-b]pyridine
CAS Number:
869335-75-1
Molecular Formula:
C8H4ClF3N2
A stable enol in small ring systems: clear differentiation between penta- and tri-valency of phosphorus atoms
Literature Information
Publication Date
2008-09-22
DOI
10.1039/B809877H
Impact Factor
6.222
Authors
Alex S. Ionkin, William J. Marshall, Brian M. Fish, Matthew F. Schiffhauer, Charles N. McEwen
View Original
Abstract
The first stable enols in 1,2-dihydrophosphetes 6 and 10 were synthesized and structurally characterized with intermolecular hydrogen bonds to phosphoryl groups in 10-membered dimeric structures; in contrast, trivalent analogue 9 exists in keto-form, where such stabilization by hydrogen bonds is not feasible.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
N,N-Diethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide
CAS Number:
325142-99-2
Molecular Formula:
C17H26BNO3
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