An organopalladium chromogenic chemodosimeter for the selective naked-eye detection of Hg2+ and MeHg+ in water–ethanol 1 : 1 mixture

Literature Information

Publication Date 2008-08-05
DOI 10.1039/B807670G
Impact Factor 6.222
Authors

O. del Campo, A. Carbayo, J. V. Cuevas, A. Muñoz, G. García-Herbosa, D. Moreno, E. Ballesteros, S. Basurto, T. Gómez, T. Torroba


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Abstract

An organopalladium chemical dosimeter of Hg2+ that methylates Hg2+, undergoing a colour change in 1 : 1 ethanol–water with submicromolar sensitivity, gives rise to an aqua–palladium complex that is methylated by MeHg+ in the presence of a dithiol compound, undergoing another colour change, thus making the system suitable for the naked-eye detection of Hg2+ and MeHg+, two environmentally important species of Hg2+.

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