Cyanide-bridged tetradecanuclear RuII3MII11clusters (MII = ZnII and CuII) based on the high connectivity building block [Ru3(HAT)(CN)12]6−: structural and photophysical properties‡

Literature Information

Publication Date 2008-07-25
DOI 10.1039/B807364C
Impact Factor 6.222
Authors

Juan Manuel Herrera, Enrique Colacio, Corine Mathonière, Duane Choquesillo-Lazarte, Michael D. Ward


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Abstract

Reaction of the anionic cyanometallate chromophore [{Ru(CN)4}3(μ3-HAT)]6− with [MII(tren)]2+ complexes (M = ZnII, CuII) provides discrete tetradecanuclear clusters of formula [{MII(tren)(μ-CN)}11{Ru3(HAT)(CN)}]16+; the weak luminescence of the Ru3 chromophore is substantially enhanced in the presence of ZnII ions, whereas it is completely quenched when CuII centers are present.

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