Cyanide-bridged tetradecanuclear RuII3MII11clusters (MII = ZnII and CuII) based on the high connectivity building block [Ru3(HAT)(CN)12]6−: structural and photophysical properties‡
Literature Information
Juan Manuel Herrera, Enrique Colacio, Corine Mathonière, Duane Choquesillo-Lazarte, Michael D. Ward
Reaction of the anionic cyanometallate chromophore [{Ru(CN)4}3(μ3-HAT)]6− with [MII(tren)]2+ complexes (M = ZnII, CuII) provides discrete tetradecanuclear clusters of formula [{MII(tren)(μ-CN)}11{Ru3(HAT)(CN)}]16+; the weak luminescence of the Ru3 chromophore is substantially enhanced in the presence of ZnII ions, whereas it is completely quenched when CuII centers are present.
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![2,6-Bis({(2R)-2-[hydroxy(diphenyl)methyl]-1-pyrrolidinyl}methyl)-4-methylphenol structure 2,6-Bis({(2R)-2-[hydroxy(diphenyl)methyl]-1-pyrrolidinyl}methyl)-4-methylphenol structure](https://static.chemtradehub.com/structs/877/877395-58-9-70bf.webp)

