Catalytic asymmetric deprotonation of phosphine boranes and sulfides as a route to P-stereogenic compounds
Literature Information
Jonathan J. Gammon, Steven J. Canipa, Peter O’Brien, Brian Kelly, Sven Taylor
A comparison between phosphine boranes and sulfides in their catalytic asymmetric deprotonation using organolithiums and sub-stoichiometric amounts of (−)-sparteine has revealed superior catalytic efficiency in the phosphine sulfide deprotonation.
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