Manipulating the cavity of a porous material changes the photoreactivity of included guests

Literature Information

Publication Date 2008-06-30
DOI 10.1039/B805895D
Impact Factor 6.222
Authors

Mahender B. Dewal, Yuewen Xu, Jun Yang, Fiaz Mohammed, Mark D. Smith, Linda S. Shimizu


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Abstract

Changing an ether to a ketone within the framework of a bis-urea macrocycle has little effect on the supramolecular assembly of this building block into porous crystals but introduces a triplet sensitizer into the framework that dramatically alters the photochemical reactions of included guests.

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