Preparation of silyl substituted crotylzinc reagents and their highly diastereoselectiveaddition to carbonyl compounds

Literature Information

Publication Date 2008-03-19
DOI 10.1039/B802157K
Impact Factor 6.222
Authors

Matthew D. Helm, Peter Mayer, Paul Knochel


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Abstract

Readily prepared β-silyl substituted crotylzinc reagents undergo highly selective allylation of carbonyl compounds leading to syn-homoallylic alcohols.

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