Indium(i) iodide-catalyzed regio- and diastereoselective formal α-addition of an α-methylallylboronate to N-acylhydrazones

Literature Information

Publication Date 2008-04-17
DOI 10.1039/B802153H
Impact Factor 6.222
Authors

Shū Kobayashi, Hideyuki Konishi, Uwe Schneider


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Abstract

Indium(I) iodide was found to catalyze the formal α-addition of an α-methylallylboronate to various N-acylhydrazones, in the presence of an alcohol additive, to afford the corresponding anti-α-adducts with high regio- and diastereoselectivity in high yields.

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