A new NCN pincer ruthenium complex and its catalytic activity for enantioselective hydrogenation of ketones

Literature Information

Publication Date 2008-03-12
DOI 10.1039/B800387D
Impact Factor 6.222
Authors

Jun-ichi Ito, Satoshi Ujiie, Hisao Nishiyama


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Abstract

New bis(oxazolinyl)phenyl–ruthenium(II) complexes, which were synthesized by C–H bond activation with RuCl3·3H2O in zinc powder and 1,5-cyclooctadine followed by ligand exchange reaction with sodium acetylacetonate or acetylacetone, exhibited enantioselective hydrogenation of ketones in up to 90% ee.

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