Heterogeneous electron transfer at Au/SAM junctions in a room-temperature ionic liquid under pressure

Literature Information

Publication Date 2008-02-25
DOI 10.1039/B719787J
Impact Factor 6.222
Authors

Peter Illner, Rudi van Eldik


View Original

Abstract

Proven electrochemical approaches were applied to study heterogeneous electron transfer (ET) between selected redox couples and gold electrodes modified with alkanethiol self-assembled monolayers (SAMs), using the room-temperature ionic liquid (RTIL) [bmim][NTf2] as reaction medium; ferrocene as freely diffusing redox probe in the RTIL was tested for ET through both thin (butanethiol) and thick (dodecanethiol) assemblages at pressures up to 150 MPa; well behaved kinetic patterns and reproducibility of data were demonstrated for ET within the unique Au/SAM/RTIL arrays.

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