Rapid formation of metal–organic nano-capsules gives new insight into the self-assembly process‡

Literature Information

Publication Date 2008-02-27
DOI 10.1039/B719769A
Impact Factor 6.222
Authors

Nicholas P. Power, John E. Warren, Jerry L. Atwood


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Abstract

Metal–organic pyrogallol[4]arene nano-capsules, mixed pyrogallol[4]arene nano-capsules, and mixed metal analogues have been rapidly synthesised by addition of excess copper nitrate to a methanol solution of the corresponding macrocycle(s) (or gallium nano-capsules for the mixed metal system); improved solubility allows for thorough study and elucidation of the assembly process for these discrete metal–organic assemblies.

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