Synthesis and structural characterisation of an yttrium–alkyl–alkylidene‡

Literature Information

Publication Date 2008-02-08
DOI 10.1039/B719633D
Impact Factor 6.222
Authors

Stephen T. Liddle, Jonathan McMaster, Jennifer C. Green, Polly L. Arnold


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Abstract

The first structurally authenticated yttrium-alkyl-alkylidene is reported; structural, spectroscopic, and theoretical analyses show that whilst the yttrium-alkylidene bond is short, it possesses a bond order less than one and is comparable to the Y–Calkyl single bond within the same molecule.

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