Asymmetric oxidation of sulfides under solvent-free or highly concentrated conditions
Literature Information
Kazuhiro Matsumoto, Tetsufumi Yamaguchi, Tsutomu Katsuki
The aluminium(salalen) complex was found to be an efficient catalyst for the asymmetric oxidation of sulfides under solvent-free or highly concentrated conditions, in which an only 0.002–0.01 mol% catalyst loading was sufficient to obtain optically active sulfoxides in high yield with high enantioselectivity.
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