Asymmetric oxidation of sulfides under solvent-free or highly concentrated conditions

Literature Information

Publication Date 2008-02-05
DOI 10.1039/B719265G
Impact Factor 6.222
Authors

Kazuhiro Matsumoto, Tetsufumi Yamaguchi, Tsutomu Katsuki


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Abstract

The aluminium(salalen) complex was found to be an efficient catalyst for the asymmetric oxidation of sulfides under solvent-free or highly concentrated conditions, in which an only 0.002–0.01 mol% catalyst loading was sufficient to obtain optically active sulfoxides in high yield with high enantioselectivity.

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