Pressure effects and Mössbauer spectroscopic studies on a 3D mixed-valence iron spin-crossover complex with NiAs topology

Literature Information

Publication Date 2008-02-11
DOI 10.1039/B718456E
Impact Factor 6.222
Authors

Yue-Ling Bai, Jun Tao, Rong-Bin Huang, Lan-Sun Zheng, Shao-Liang Zheng, Kazuyoshi Oshida, Yasuaki Einaga


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Abstract

A three-dimensional mixed-valence iron complex with NiAs-type topology, [(FeIII3O)FeII(TA)6(H2O)3]·(ClO4)2(NO3)(EtOH)(H2O)2 (1, HTA = tetrazole-1H-acetic acid), shows spin-crossover behavior that was characterized via variable-temperature crystal structures, Mössbauer spectra and magnetic susceptibilities, the pressure effects on the transition behavior were also studied.

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