Reactivity of a coordinatively unsaturated Cp*Ru(κ2-P,O) complex

Literature Information

Publication Date 2007-10-25
DOI 10.1039/B713386C
Impact Factor 6.222
Authors

Matthew A. Rankin, Kevin D. Hesp, Gabriele Schatte, Robert McDonald, Mark Stradiotto


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Abstract

Whereas a new coordinatively unsaturated Cp*Ru(κ2-P,O) complex (1a) forms adducts with two-electron donors (including σ-H2 and µ-N2 ligands), double Si–H bond activation is observed upon treatment with Ph2SiH2 or PhSiH3, leading to the clean formation of products corresponding to the net insertion of a Ph2Si: or Ph(H)Si: fragment into the Ru–O bond of 1a.

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