Crabtree's catalyst revisited; Ligand effects on stability and durability
Literature Information
Yingjian Xu, D. Michael P. Mingos, John M. Brown
The extent of time-dependent deactivation of monophosphine monoamine iridium hydrogenation catalysts by trimer formation is strongly dependent on ligand structure; attempts to counter this process lead to the observation of an oligomerisation resistant catalyst.
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