Formation of two (6,3) networks showing structural diversity, Borromean topology and conformational chirality in the same crystal

Literature Information

Publication Date 2007-08-07
DOI 10.1039/B709118D
Impact Factor 6.222
Authors

Xue-Li Zhang, Cui-Ping Guo, Qing-Yuan Yang, Wei Wang, Wei-Sheng Liu, Bei-Sheng Kang, Cheng-Yong Su


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Abstract

Reaction of two tripodal ligands, 2,4,6-tris(4-((2-methyl-benzimidazol-1-yl)methyl)phenyl)-1,3,5-triazine (L111) and 1,3,5-tris(4-((2-methyl-benzimidazol-1-yl)methyl)phenyl)benzene (L222), with AgSbF6 led to formation of two types (6,3) networks in one single crystal, of which one is three-fold Borromean topologically entangled while the other is independent, showing the same chirality and sandwiched Borromean stacking.

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