Assembly between gold-thiolate nanoparticles and the organometallic cluster [Fe(η5-C5H5)(µ3-CO)]4 toward redox sensing of oxo-anions

Literature Information

Publication Date 2007-07-25
DOI 10.1039/B708466H
Impact Factor 6.222
Authors

Jaime Ruiz Aranzaes, Colette Belin, Didier Astruc


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Abstract

Covalent assembly between gold-thiolate nanoparticles (AuNPs) and the cluster [Fe(η5-C5H5)(µ3-CO)]4, 1, can be achieved either by direct Brust–Schriffin-type synthesis using a mixture of undecanethiol and a thiol functionalized with 1, or by substitution of undecanethiolate ligands in AuNPs by thiolate ligands functionalized with 1; cyclic voltammetry of these AuNPs functionalized with 1 allows us to recognize and titrate the oxo-anions H2PO4– and ATP2–.

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