Sulfonylvs.carbonyl group: which is the more electron-withdrawing?
Literature Information
Publication Date
2007-06-07
DOI
10.1039/B705034H
Impact Factor
6.222
Authors
Isabelle Chataigner, Cécilia Panel, Hélène Gérard, Serge R. Piettre
View Original
Abstract
Unexpectedly high reactivity of nitrogenated aromatics protected as amides or carbamates, when compared to sulfonamides, can be explained by a decrease of the aromaticity due to a greater ability of the carbon-centered groups to achieve delocalisation of the nitrogen lone pair, resulting in stronger global withdrawing effects.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
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2458
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