Enhanced reactivity of hydrophobic vitamin B12 towards the dechlorination of DDT in ionic liquid

Literature Information

Publication Date 2007-03-23
DOI 10.1039/B700725F
Impact Factor 6.222
Authors

Md. Abdul Jabbar, Hisashi Shimakoshi, Yoshio Hisaeda


View Original

Abstract

The electrolytic reductive dechlorination of 1,1-bis(p-chlorophenyl)-2,2,2-trichloroethane (DDT) in the ionic liquid (IL) 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]) in the presence of a cobalamin derivative afforded 1,1′-(ethylidene)bis(4-chlorobenzene) (DDO) and 1,1′-(ethenylidene)bis(4-chlorobenzene) (DDNU) with 1,1′-(2-chloroethylidene)bis(4-chlorobenzene) (DDMS); the enhanced reactivity, as well as the recyclability of the cobalamin derivative catalyst in IL, makes the present system more efficient for the development of “green” technologies.

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