A high-performance selective oxidation system for the facile production of fine chemicals

Literature Information

Publication Date 2007-04-19
DOI 10.1039/B618090F
Impact Factor 6.222
Authors

Robert Raja, John Meurig Thomas, Mike Greenhill-Hooper, Violeta Doukova


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Abstract

MnIIIAlPO-5 and CrVIAlPO-5 redox (microporous) catalysts are effective, in the presence of dissolved acetylperoxyborate (APB) under mild conditions (333–373 K), and much superior to the titanosilicate, TS-1 (also a single-site heterogeneous catalyst), in the selective oxidation of primary, secondary, benzylic and other unsaturated alcohols, p-cymene, methyl cyclohexene and other speciality organics which are of value in the fine-chemical and pharmaceutical industries.

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Chemical Communications
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