Reusable and environmentally friendly ionic trinuclear iron complex catalyst for atom transfer radical polymerization

Literature Information

Publication Date 2007-02-15
DOI 10.1039/B617722K
Impact Factor 6.222
Authors

Shota Niibayashi, Hitoshi Hayakawa, Ren-Hua Jin, Hideo Nagashima


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Abstract

Ionic iron complex [(Me3tacn)2Fe2Cl3]+[(Me3tacn)FeCl3]− (1), which is readily soluble in methanol, acted as a powerful catalyst in controlled radical polymerization of styrene and MMA, and showed promising features of removal from the resulting polymers and was reusable after recovery from the crude products.

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