From inconsistent results to high speed hydrosilylation

Literature Information

Publication Date 2007-01-10
DOI 10.1039/B617413B
Impact Factor 6.222
Authors

Virginie Comte, Cédric Balan, Pierre Le Gendre, Claude Moïse


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Abstract

After noting that the presence of dihydrogen, generated in situ from the partial hydrolysis of a silane with residual water, significantly enhances the rate of the rhodium-catalysed hydrosilylation of acetophenone, we developed a high speed hydrosilylation reaction under dihydrogen pressure.

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