Enantioselective palladium-catalysed conjugate addition of arylsiloxanes

Literature Information

Publication Date 2007-01-18
DOI 10.1039/B616969D
Impact Factor 6.222
Authors

Francesca Gini, Bart Hessen, Ben L. Feringa, Adriaan J. Minnaard


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Abstract

The complex formed from Pd(CH3CN)4(BF4)2 and (R,R)-MeDUPHOS is a highly enantioselective catalyst for the asymmetric conjugate addition of aryltriethylsiloxanes to a variety of unsaturated ketones, lactones and lactams.

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