57Fe Mössbauer spectroscopy predicts superstructure for K0.08[CuII(N,N′app)Cl]2[FeIII(CN)6]·0.92H3O·3H2O

Literature Information

Publication Date 2007-03-07
DOI 10.1039/B615130B
Impact Factor 6.222
Authors

Uday Mukhopadhyay, C. Matthias Grunert, Joachim Kusz, Sergey Reiman, P. Gütlich, Ivan Bernal


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Abstract

The compound [Cu(N,N′app)Cl]2[Fe(CN)6]·xH2O, with N,N′app being bis(N,N′-3-aminopropylpiperazine), was prepared and its structure determined by single crystal X-ray analysis, confirming a ratio of two copper complexes to one iron complex; 57Fe Mössbauer spectra showed three quadrupole doublets typical of iron(III) low spin species which call for the presence of a superstructure.

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