Regioselective [2 + 2]-photocycloaddition reactions of chiral tetronates—influence of temperature, pressure, and reaction medium‡
Literature Information
Martin Fleck, Cheng Yang, Takehiko Wada, Yoshihisa Inoue, Thorsten Bach
The intramolecular [2 + 2]-photocycloaddition of the 1,3-divinyl-2-cyclopentyl tetronates 1 was performed under various conditions to give perfect diastereoselectivity and a regioselectivity of up to 85/15 in the presence of γ-cyclodextrin by differentiating the two chemically very similar double bonds of 1.
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![N-[4-(Cyanoethynyl)phenyl]-16-oxo-4,7,10,13-tetraoxa-17-azahenicos-1-yn-21-amide structure N-[4-(Cyanoethynyl)phenyl]-16-oxo-4,7,10,13-tetraoxa-17-azahenicos-1-yn-21-amide structure](https://static.chemtradehub.com/structs/218/2183440-36-8-68cb.webp)
