Photochemical asymmetric synthesis of phenyl-bearing quaternary chiral carbons using chiral-memory effect on β-hydrogen abstraction by thiocarbonyl group
Literature Information
Masami Sakamoto, Hiroya Kawanishi, Takashi Mino, Yoshio Kasashima, Tsutomu Fujita
Quaternary chiral carbons were effectively generated from tertiary chiral carbons via photochemical intramolecular β-hydrogen abstraction reaction of thioimides involving the highly-controlled chiral-memory effect.
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