Photochemical asymmetric synthesis of phenyl-bearing quaternary chiral carbons using chiral-memory effect on β-hydrogen abstraction by thiocarbonyl group

Literature Information

Publication Date 2006-09-25
DOI 10.1039/B608513J
Impact Factor 6.222
Authors

Masami Sakamoto, Hiroya Kawanishi, Takashi Mino, Yoshio Kasashima, Tsutomu Fujita


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Abstract

Quaternary chiral carbons were effectively generated from tertiary chiral carbons via photochemical intramolecular β-hydrogen abstraction reaction of thioimides involving the highly-controlled chiral-memory effect.

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