Novel aziridination of olefins: direct synthesis from sulfonamides using t-BuOI

Literature Information

Publication Date 2006-06-30
DOI 10.1039/B606499J
Impact Factor 6.222
Authors

Satoshi Minakata, Yoshinobu Morino, Yoji Oderaotoshi, Mitsuo Komatsu


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Abstract

tert-Butyl hypoiodite (t-BuOI) was found to be a powerful reagent for synthesis of aziridines from olefins and sulfonamides. The aziridination of olefins was achieved by using sulfonamides with t-BuOI. Our preliminary findings represent the example of metal-free aziridination of olefins with readily accessible sulfonamides as a nitrogen source.

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