Iron hydrogenase active site mimic holding a proton and a hydride

Literature Information

Publication Date 2005-12-20
DOI 10.1039/B514280F
Impact Factor 6.222
Authors

Gerriet Eilers, Lars Eriksson, Adolf Gogoll, Reiner Lomoth


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Abstract

The first model of the iron hydrogenase active site has been prepared which concomitantly carries a proton and a hydride; the title species was characterized by IR and NMR spectroscopy and is reduced at more positive potential than any other mimic of this kind.

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Chemical Communications

Chemical Communications
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