Novel HEXOL-type cyclometallated iridium(iii) complexes: stereoselective synthesis and structure elucidation

Literature Information

Publication Date 2005-07-28
DOI 10.1039/B507769A
Impact Factor 6.222
Authors

Liangru Yang, Alex von Zelewsky, Helen Stoeckli-Evans


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Abstract

Two diastereoisomers of tetranuclear cyclometallated iridium complexes, either having an inner core of HEXOL-type [Ir(IrCl2)3]6+ unit and a surface of six chiral, didentate, cyclometallated ligands, are stereoselectively synthesized from an enantiopure pinenopyridine derivative.

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