Relevance of electron transfer mechanism in electrocatalysis: the reduction of organic halides at silver electrodes

Literature Information

Publication Date 2005-12-02
DOI 10.1039/B513801A
Impact Factor 6.222
Authors

Abdirisak A. Isse, Luigi Falciola, Patrizia R. Mussini, Armando Gennaro


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Abstract

The mechanism of dissociative electron transfer (ET) to a series of organic chlorides has been investigated both at an inert electrode and at a catalytic surface such as Ag; electrocatalysis is important only when breaking of the carbon–halogen bond is concerted with the ET.

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