Synthesis and magnetic properties of a 4-(2′-pyrimidyl)-1,2,3,5-dithiadiazolyl dimanganese complex

Literature Information

Publication Date 2005-11-25
DOI 10.1039/B512312G
Impact Factor 6.222
Authors

Michael Jennings, Kathryn E. Preuss, Jian Wu


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Abstract

A spin-bearing bis-bidentate ligand, designed from a pyrimidyl-substituted R-CN2S2 neutral radical, is used to co-ordinate two Mn(II) metal centres yielding a thermally stable complex with antiferromagnetic coupling between the ligand-centred spin and the metal-centred spins, and thus an overall ferrimagnetic coupling scheme with a ground state S = 9/2.

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