Strategies to develop methods using ion-molecule reactions in a quadrupole reaction cell to overcome spectral overlaps in inductively coupled plasma mass spectrometry

Literature Information

Publication Date 2005-12-06
DOI 10.1039/B511464K
Impact Factor 4.023
Authors


View Original

Abstract

ICP-MS instruments that use ion-molecule reactions to overcome spectral overlaps are becoming more widely available. Strategies to develop methods that use ion-molecule reactions in a quadrupole reaction cell are systematically described. Ion-molecule reactions may be used to remove the spectral overlap ion so that the analyte elemental ion can be measured with little background. Alternatively, ion-molecule reactions can be used to produce a new analyte-containing product ion at a higher mass where the background is low. Considerations for each approach including selection of the reaction gas, adjustment of the reaction cell bandpass and optimization of the gas flow rate are discussed. Examples are given with available kinetic rate constants, thermodynamic data and experimental ICP-MS measurements to illustrate each consideration in development of methods using ion-molecule reactions. Rejection of reactant ions from the cell in order to prevent generation of undesired reaction product ions is quantitatively assessed.

Related Literature

Different routes to methanol: inelastic neutron scattering spectroscopy of adsorbates on supported copper catalysts

Timur Kandemir, Matthias Friedrich, Stewart F. Parker, Felix Studt, David Lennon, Robert Schlögl, Malte Behrens

2016-04-14 Paper

DOI: 10.1039/C6CP00967K

Defect induced tunable near infrared emission of Er–CeO2 by heterovalent co-dopants

Mihaela Florea, Daniel Avram, Bogdan Cojocaru, Ion Tiseanu, Vasile Parvulescu, Carmen Tiseanu

2016-06-03 Paper

DOI: 10.1039/C6CP02754G

Long-living optical gain induced by solvent viscosity in a push–pull molecule

M. M. Mróz, S. Benedini, A. Forni, C. Botta, D. Pasini, E. Cariati, T. Virgili

2016-06-08 Paper

DOI: 10.1039/C6CP02988D

Surface adsorption of sulfonated poly(phenylene sulfone)/C14TAB mixtures and its correlation with foam film stability

Martin Uhlig, Reinhard Miller, Regine von Klitzing

2016-06-17 Paper

DOI: 10.1039/C6CP02256A

Enhanced photocatalytic activity of a self-stabilized synthetic flavin anchored on a TiO2 surface

Manjula Pandiri, Mohammad S. Hossain, Frank W. Foss, Jr., Krishnan Rajeshwar, Yaron Paz

2016-06-13 Paper

DOI: 10.1039/C6CP02060G

The application of inelastic neutron scattering to investigate the interaction of methyl propanoate with silica

Andrew R. McFarlane, Hannah Geller, Ian P. Silverwood, Richard I. Cooper, David J. Watkin, Stewart F. Parker, John M. Winfield, David Lennon

2016-05-09 Paper

DOI: 10.1039/C6CP01276K

Structure and bonding in crystalline cesium uranyl tetrachloride under pressure

Pilar Pertierra, Miguel A. Salvadó, F. Izquierdo-Ruiz, J. M. Recio

2016-06-10 Paper

DOI: 10.1039/C6CP03876J

You might also like

Compound Q&A

What regulatory guidelines apply to 4-Amino-3-bromophenol (CAS: 74440-80-5)?

4-Amino-3-bromophenol (CAS: 74440-80-5) falls under the classification of a haza...

74440-80-54-Amino-3-bromopheno...
Compound Q&A

How should (17beta)-3-Oxoestr-4-en-17-yl acetate (CAS: 1425-10-1) be stored?

(17beta)-3-Oxoestr-4-en-17-yl acetate should be stored in a cool, dry place away...

1425-10-1(17beta)-3-Oxoestr-4...
Compound Q&A

What are the physical and chemical properties of 2-[(2,2-Diethoxyethyl)disulfanyl]-1,1-diethoxyethane (CAS: 76505-71-0)?

2-[(2,2-Diethoxyethyl)disulfanyl]-1,1-diethoxyethane (CAS: 76505-71-0) is a colo...

76505-71-02-[(2,2-Diethoxyethy...
Compound Q&A

What is the market or research trend for 1-(β-D-ribofuranosyl)-1H-imidazo[4,5-c]pyridin-4-amine?

The market and research for 1-(β-D-ribofuranosyl)-1H-imidazo[4,5-c]pyridin-4-ami...

6736-58-91-(beta-D-Ribofurano...
Compound Q&A

How should waste containing Conjugated Estrogen (CAS: 12126-59-9) be handled?

Waste containing Conjugated Estrogen (CAS: 12126-59-9) should be collected and d...

12126-59-9Conjugated Estrogen
Compound Q&A

What is the market or research trend for Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate?

The market for Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate (CAS...

88738-78-7Bis(2,2,2-trifluoroe...
Compound Q&A

Are there alternatives to 3,4'-Di-O-methylellagic acid (CAS: 57499-59-9) in synthesis?

There are several alternatives to 3,4'-Di-O-methylellagic acid (CAS: 57499-59-9)...

57499-59-93,4'-Di-O-methylella...
Compound Q&A

What regulatory guidelines apply to 2-Chloro-N,N-dimethylpyridin-4-amine (CAS: 59047-70-0)?

2-Chloro-N,N-dimethylpyridin-4-amine (CAS: 59047-70-0) is regulated under the Gl...

59047-70-02-Chloro-N,N-dimethy...
Compound Q&A

What is cerium(3+);oxygen(2-);vanadium(5+) (CAS: 13597-19-8)?

Cerium(3+);oxygen(2-);vanadium(5+) (CAS: 13597-19-8) is a complex inorganic comp...

13597-19-8cerium(3+);oxygen(2-...
Compound Q&A

Is 7-Chloro-1-iodoisoquinoline (CAS: 1203579-27-4) safe?

7-Chloro-1-iodoisoquinoline (CAS: 1203579-27-4) is generally considered safe whe...

1203579-27-47-Chloro-1-iodoisoqu...

Source Journal

Journal of Analytical Atomic Spectrometry

Journal of Analytical Atomic Spectrometry
CiteScore: 6.2
Self-citation Rate: 25.8%
Articles per Year: 254

The Journal of Analytical Atomic Spectrometry (JAAS) is the central journal for publishing innovative research on fundamentals, instrumentation, and methods in the determination, speciation and isotopic analysis of (trace) elements within all fields of application. This includes, but is not restricted to, the most recent progress, developments and achievements in all forms of atomic and elemental detection, isotope ratio determination, molecular analysis, plasma-based analysis and X-ray techniques. The journal welcomes full papers, communications, technical notes, critical and tutorial review articles, editorials, and comments, in addition to the Atomic Spectrometry Updates (ASU) literature reviews that are prepared by an expert panel. Submissions are welcome in the following areas, but note this list reflects the current scope and authors are strongly encouraged to contact the Editorial team if they believe that their work offers potentially new and emerging research relevant to the journal remit: Fundamental studies in the following. New and existing sources for atomic emission, absorption, fluorescence and mass spectrometry and those that provide both atomic and molecular information Sample introduction techniques for solids, liquids, gases Improvements in sensitivity, selectivity, precision, accuracy and/or robustness Isotope ratio measurements, including techniques for improving precision and mass bias correction Single channel and multichannel simultaneous detection systems Chemometrics, statistics, calibration techniques and internal standardisation Theoretical and numerical modelling of fundamental processes related to all of the above methodologies Novel or improved methodologies in areas of application including, but not limited to the following. Biosciences, including elemental, speciation and isotopic analysis in biological systems, immunoassays based on metal-labeled antibodies, bio-imaging, and nanoparticle toxicology Geochemistry Environmental science Materials science, including engineered nanoparticles and quantum dots Metrology, including reference materials Forensic analysis Food and agricultural sciences Energy Archaeometry Molecular analysis. Molecular sources for elemental and isotopic analysis Atomic sources for molecular analysis Atomic and molecular techniques simultaneously used for complementary chemical information All contributions are judged on originality and quality of scientific content, and appropriateness of length to content of new science.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.