A novel route for in-situ H2O2 generation from selective reduction of O2 by hydrazine using heterogeneous Pd catalyst in an aqueous medium
Literature Information
Publication Date
2005-10-03
DOI
10.1039/B510543A
Impact Factor
6.222
Authors
Vasant R. Choudhary, Chanchal Samanta, Prabhas Jana
View Original
Abstract
Hydrogen peroxide in high yields can be generated with high efficiency at mild conditions (25 °C and atmospheric pressure) with the formation of only environment-friendly by-products (N2 and H2O) by a reduction of O2 by hydrazine from its hydrate/salt with its complete conversion in a short reaction period (≤0.5 h) using a easily separable supported Pd catalyst (Pd/Al2O3, Pd/Ga2O3 or Pd/C) in an acidic aqueous medium in the presence of bromide anions; the presence of both acid (protons) and bromide anions is essential for the selective reduction of O2 by hydrazine to H2O2 and in their absence, the reaction leads only to the formation of water.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
Trichloro(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane
CAS Number:
78560-45-9
Molecular Formula:
C8H4Cl3F13Si
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