A microchip capillary electrophoretic reactor: a new methodology for direct measurement of dissociation kinetics of metal complexes

Literature Information

Publication Date 2005-08-08
DOI 10.1039/B509546H
Impact Factor 4.616
Authors

Toru Takahashi, Kei-ichirou Ohtsuka, Nobuhiko Iki, Hitoshi Hoshino


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Abstract

A microchip capillary electrophoretic reactor has been proposed and successfully demonstrated in the direct evaluation of the solvolytic dissociation rate constant of the complex of Ce3+ with a polyaminocarboxylic ligand, 8-amino-2-[(2-amino-5-methylphenoxyl)methyl]-6-methoxyquinoline-N,N,N′,N′-tetraacetic acid.

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