Diastereoselective Ni(0)-catalyzed carbocyclization to chiral vinylic sulfoxide

Literature Information

Publication Date 2005-07-11
DOI 10.1039/B506375B
Impact Factor 6.222
Authors

Naoyoshi Maezaki, Hiroaki Sawamoto, Hiroyuki Ishihara, Tetsuaki Tanaka


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Abstract

Diastereoselective Ni(0)-catalyzed carbocyclization of enone to chiral vinylic sulfoxide has been accomplished, wherein two stereogenic centers were constructed simultaneously to give cis- and trans-disubstituted cyclopentanes from (E)- and (Z)-vinylic sulfoxides, respectively.

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