A chiral porous 3D metal–organic framework with an unprecedented 4-connected network topology

Literature Information

Publication Date 2005-06-15
DOI 10.1039/B505916J
Impact Factor 6.222
Authors

Chuan-De Wu, Wenbin Lin


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Abstract

A novel homochiral 3D metal–organic framework [CdL2(H2O)2][ClO4]2·2DMF·3EtOH·5/3H2O, 1, (L = (R)-6,6′-dichloro-2,2′-diethoxy-1,1′-binaphthyl-4,4′-bipyridine) exhibits an unprecedented 4-connected network topology owing to the cis- configuration of the Cd coordination and possesses permanent porosity as demonstrated by TGA, XRPD, and CO2 adsorption isotherm studies.

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