Solvolytic routes to new nonabismuth hydroxy- and alkoxy-oxo complexes: synthesis, characterization and solid-state structures of novel nonabismuth polyoxo cations Bi9(μ3-O)8(μ3-OR)65+ (R = H, Et)

Literature Information

Publication Date 2005-07-27
DOI 10.1039/B504864H
Impact Factor 6.222
Authors

John H. Thurston, Dale C. Swenson, Louis Messerle


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Abstract

Base hydrolysis of BiO(ClO4) yields ClO4− salts of the novel nonabismuth polyoxo cation Bi9(μ3-O)8(μ3-OH)65+ (1); ethanolysis converts 1 to the ethoxide Bi9(μ3-O)8(μ3-OEt)65+ (2).

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