NaOH-catalyzed crossed Claisen condensation between ketenesilylacetals and methyl esters
Literature Information
Publication Date
2005-05-20
DOI
10.1039/B504750A
Impact Factor
6.222
Authors
Akira Iida, Kenta Takai, Tomohito Okabayashi, Tomonori Misaki, Yoo Tanabe
View Original
Abstract
We have developed a practical crossed Claisen condensation between ketene silyl acetals and methyl esters using catalytic NaOH to obtain α-monoalkylated β-keto esters and inaccessible α,α-dialkylated β-keto esters.
Related Literature
Fermentation of hydrolysate detoxified by pervaporation through block copolymer membranes
Douglas R. Greer, Thalita P. Basso, Ana B. Ibanez, Stefan Bauer, Jeffrey M. Skerker, A. Evren Ozcam, Dacia Leon, Chaeyoung Shin, Adam P. Arkin
2014-07-11
Paper
DOI: 10.1039/C4GC00756E
Hydrothermal decarboxylation of amino acid derived imidazolium zwitterions: a sustainable approach towards ionic liquids
Sarah Kirchhecker, Markus Antonietti, Davide Esposito
2014-05-08
Communication
DOI: 10.1039/C4GC00564C
Combination of Pd/C and Amberlyst-15 in a single reactor for the acid/hydrogenating catalytic conversion of carbohydrates to 5-hydroxy-2,5-hexanedione
Fei liu, Maïté Audemar, Karine De Oliveira Vigier, Jean-Marc Clacens, Floryan De Campo, François Jérôme
2014-07-25
Communication
DOI: 10.1039/C4GC01158A
Tunable thermomorphism and applications of ionic liquid analogues of Girard's reagents
Marijana Blesic, H. Q. Nimal Gunaratne, Johan Jacquemin, Peter Nockemann, Sonia Olejarz, Kenneth R. Seddon, Christopher R. Strauss
2014-08-06
Communication
DOI: 10.1039/C4GC01159G
Visible-light-induced photocatalytic formyloxylation reactions of 3-bromooxindoles with water and DMF: the scope and mechanism
You-Quan Zou, Wei Guo, Feng-Lei Liu, Liang-Qiu Lu, Jia-Rong Chen
2014-05-08
Paper
DOI: 10.1039/C4GC00647J
Structural–functional evaluation of ionic liquid libraries for the design of co-solvents in lipase-catalysed reactions
João V. Rodrigues, Diana Ruivo, Ana Rodríguez, Francisco J. Deive, José M. S. S. Esperança, Isabel M. Marrucho, Cláudio M. Gomes, Luís Paulo N. Rebelo
2014-08-04
Communication
DOI: 10.1039/C4GC01329H
Hydrogenation of levulinic acid to γ-valerolactone by Ni and MoOx co-loaded carbon catalysts
Shota Kanno, Kenichi Kon
2014-06-05
Paper
DOI: 10.1039/C4GC00735B
Correction: Catalytic aerobic oxidation of renewable furfural to maleic anhydride and furanone derivatives with their mechanistic studies
Jihong Lan, Zhuqi Chen, Jinchi Lin, Guochuan Yin
2014-09-10
Correction
DOI: 10.1039/C4GC90039A
Continuous production of sugars from pyrolysis of acid-infused lignocellulosic biomass
2014-06-17
Paper
DOI: 10.1039/C4GC00602J
You might also like
Compound Q&A
How should 2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) be stored?
2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) should be stored in ...
615-45-22-Methylbenzene-1,4-...
Compound Q&A
Is (1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide (CAS: 132747-20-7) safe?
(1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide is generally considered sa...
132747-20-7(1S,4S)-2,5-Diazabic...
Compound Q&A
What industries use (6-Chloropyridazin-3-YL)methanamine (CAS: 871826-15-2)?
(6-Chloropyridazin-3-YL)methanamine finds applications in the pharmaceutical ind...
871826-15-2(6-Chloropyridazin-3...
Compound Q&A
What are the main uses of 2-Fluoro-3-methylphenol (CAS: 77772-72-6)?
2-Fluoro-3-methylphenol is primarily used in the synthesis of pharmaceuticals, p...
77772-72-62-Fluoro-3-methylphe...
Compound Q&A
What precautions should be taken when handling 3-Methoxy-4-nitrobenzonitrile (CAS: 177476-75-4)?
When handling 3-Methoxy-4-nitrobenzonitrile, it is important to wear appropriate...
177476-75-43-Methoxy-4-nitroben...
Compound Q&A
What precautions should be taken when handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4)?
When handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4), it is ...
211949-57-4[1,3]Oxazolo[4,5-b]p...
Compound Q&A
What regulatory guidelines apply to 4-Ethynylbenzamide (CAS: 90347-86-7)?
4-Ethynylbenzamide (CAS: 90347-86-7) falls under various regulatory guidelines i...
90347-86-74-Ethynylbenzamide
Compound Q&A
What are the main uses of 3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone (CAS: 186822-57-1)?
3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone is primarily used as an intermediat...
186822-57-13-(2-Ethylphenyl)-2-...
Compound Q&A
What is (2-Fluoro-6-methoxyphenyl)acetic acid (CAS: 500912-19-6)?
(2-Fluoro-6-methoxyphenyl)acetic acid, also known as 4-fluoro-3-methoxybenzoic a...
500912-19-6(2-Fluoro-6-methoxyp...
Compound Q&A
What is the market or research trend for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9)?
Market trends for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9) indicat...
102196-18-92-[4-(Hydroxymethyl)...
Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
![(1R,6R)-6-({[(2-Methyl-2-propanyl)oxy]carbonyl}amino)-3-cyclohexene-1-carboxylic acid structure](https://static.chemtradehub.com/structs/865/865689-24-3-5fef.webp "(1R,6R)-6-({[(2-Methyl-2-propanyl)oxy]carbonyl}amino)-3-cyclohexene-1-carboxylic acid structure")
(1R,6R)-6-({[(2-Methyl-2-propanyl)oxy]carbonyl}amino)-3-cyclohexene-1-carboxylic acid
CAS Number:
865689-24-3
Molecular Formula:
C12H19NO4
![1-Benzyl-1,7-diazaspiro[4.4]nonane dihydrochloride structure](https://static.chemtradehub.com/structs/115/1159822-71-5-0320.webp "1-Benzyl-1,7-diazaspiro[4.4]nonane dihydrochloride structure")
1-Benzyl-1,7-diazaspiro[4.4]nonane dihydrochloride
CAS Number:
1159822-71-5
Molecular Formula:
C14H22Cl2N2
![1H-Imidazo[4,5-c]pyridine-7-carboxylic acid structure](https://static.chemtradehub.com/structs/123/1234616-39-7-1344.webp "1H-Imidazo[4,5-c]pyridine-7-carboxylic acid structure")
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.