Spontaneous assembly of a nine-vertex lithium framework encapsulating the peroxide dianion

Literature Information

Publication Date 2005-05-18
DOI 10.1039/B504022A
Impact Factor 6.222
Authors

Martyn P. Coles, Peter B. Hitchcock


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Abstract

Investigation of the structure of the lithiated bicyclic guanidine 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine (hppH) has led to the reproducible isolation of compounds containing the ‘Li9(hpp)7(O2)’ core, in which a peroxide dianion has been encapsulated within a mono-capped, cubic array of lithium ions.

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