Unprecedented use of silver(i) N-heterocyclic carbene complexes for the catalytic preparation of 1,2-bis(boronate) esters

Literature Information

Publication Date 2005-05-06
DOI 10.1039/B503239C
Impact Factor 6.222
Authors

Jesus Ramírez, Rosa Corberán, Mercedes Sanaú, Eduardo Peris, Elena Fernandez


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Abstract

Catalytic diboration of internal and terminal alkenes with Ag(I) N-heterocyclic carbene complexes leads to 1,2-bis(boronate) esters as single intermediates, that can be oxidised towards the corresponding diols.

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