Regio- and stereoselective synthesis of enantiomerically pure [60]fullerene tris-adducts with an inherently chiral e,e,e addition pattern

Literature Information

Publication Date 2005-06-15
DOI 10.1039/B502822A
Impact Factor 6.222
Authors

Nikos Chronakis, Andreas Hirsch


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Abstract

The synthesis and flash column chromatographic separation of enantiomerically pure tris-adducts of C60 with an e,e,e-addition pattern is achieved via cyclopropanation with chiral D3-symmetrical cyclo-tris(malonate) tethers.

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