Characterisation of the water/o-nitrophenyl octyl ether system in terms of the partition of nonelectrolytes and of ions

Literature Information

Publication Date 2005-05-19
DOI 10.1039/B502058A
Impact Factor 3.676
Authors

Michael H. Abraham, Yuan H. Zhao


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Abstract

The Abraham linear free energy relationship, or solvation equation, has been applied to literature data on the partition of nonelectrolytes in the water to o-nitrophenyl octyl ether (NPOE) system. The resulting equation is compared to equations for other water to solvent systems using the D-parameter of Abraham and Martins and the θ-parameter of Ishihama and Asakawa. It is shown that as a solvent in partitioning systems, NPOE quite resembles nitrobenzene and 1,2-dichloroethane, and that the latter does not resemble an alkane-like solvent. Using descriptors for simple ions that we have previously obtained, we show that ions and nonelectrolytes can be included in the same linear free energy relationship.

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Physical Chemistry Chemical Physics
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