A new class of organic donor–acceptor molecules with large third-order optical nonlinearities

Literature Information

Publication Date 2005-01-17
DOI 10.1039/B417393G
Impact Factor 6.222
Authors

Tsuyoshi Michinobu, Joshua C. May, Jin H. Lim, Corinne Boudon, Jean-Paul Gisselbrecht, Paul Seiler, Maurice Gross, Ivan Biaggio, François Diederich


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Abstract

Donor–acceptor molecules with 4-(dimethylamino)phenyl donor and 1,1,4,4-tetracyanobuta-1,3-diene acceptor moieties are readily prepared by short, high-yielding routes. The quite small chromophores are characterised by X-ray crystallography and feature intense intramolecular charge-transfer bands, substantial quinoid character in the donor rings, reversible electrochemical reductions and oxidations and powerful third-order optical nonlinearities.

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