High resolution FTIR spectroscopy of the ν1 band of NSCl
Literature Information
Evan G. Robertson, Christopher D. Thompson, Sebastian Lucie, Don McNaughton
The highly reactive molecule thiazyl chloride (NSCl) prepared by pyrolysis of S3N2Cl2 at 70 °C was measured by high resolution (0.003 cm−1) FTIR spectroscopy in the mid-IR region. Detailed analyses of ν1, the hybrid a/b-type band at 1325.6 cm−1, led to assignment of 6275 and 3836 lines, respectively, for the 14N32S35Cl and 14N32S37Cl isotopomers. Fitting to Watson’s A-reduced Hamiltonian led to the first rovibrational constants for the ν1 mode along with an improved set of ground state constants including centrifugal distortion beyond the quartic level.
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