A new type of nonsulfide hydrotreating catalyst: nickel phosphide on carbon

Literature Information

Publication Date 2005-01-12
DOI 10.1039/B415838E
Impact Factor 6.222
Authors

Yuying Shu, S. Ted Oyama


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Abstract

Nickel phosphide on carbon is successfully synthesized by temperature-programmed reduction as verified with X-ray diffraction and extended X-ray absorption fine structure measurements; it shows superior activity, selectivity, and stability for sulfur removal from the refractory compound 4,6-dimethyldibenzothiophene with a steady-state conversion of 99%, which is much higher than that of a commercial NiMoS/γ-Al2O3 catalyst of 68%.

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