Reactivity of cobalt dimer and molecular oxygen in rare gas matrices. IR spectrum, photophysics and structure of Co2O2

Literature Information

Publication Date 2005-01-24
DOI 10.1039/B415420G
Impact Factor 3.676
Authors

Delphine Danset, Laurent Manceron


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Abstract

The reactivity of cobalt dimer towards molecular oxygen has been investigated in rare gas matrices. If the formation of Co2O2 from the condensation of effusive beams of Co and O2 in neon and argon matrices is observed after sample deposition, our results show that the in situ formation does not result from the reaction of ground state Co nor Co2 with molecular oxygen. One reaction channel has been evidenced through reaction of Co2 in excited states, close or above the dissociation limit. Two metastable states of Co2O2 with low-symmetry structures, stabilized by interaction with the matrix cage have also been evidenced between 1.4 and 2 eV above the ground state. Observation of Co216O2, Co218O2 and Co216O18O isotopic data for five fundamental and three combination transitions enable determination of all fundamental vibrations for matrix-isolated Co2O2 in its cyclic ground state. Semi-empirical harmonic potential calculations lead to estimates of 2.435 N cm−1 for the Co–O bond force constant, and 93 ± 5° OCoO bond angle. In comparison with the CoO diatomic molecule, this suggests a near square-planar structure with a 1.765 ± 0.01 Å CoO bond distance.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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