New catalytic route to functionalized vinylboronates
Literature Information
Bogdan Marciniec, Magdalena Jankowska, Cezary Pietraszuk
Vinylsubstituted boronates i.e. vinyldioxaborolane and vinyldioxaborinane react regioselectively with olefins in the presence of RuHCl(CO)(PCy3)2 with the formation of functionalized vinylboron derivatives. The reaction opens a new catalytic route for preparation of organoboranes.
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