New catalytic route to functionalized vinylboronates

Literature Information

Publication Date 2004-12-14
DOI 10.1039/B414644A
Impact Factor 6.222
Authors

Bogdan Marciniec, Magdalena Jankowska, Cezary Pietraszuk


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Abstract

Vinylsubstituted boronates i.e. vinyldioxaborolane and vinyldioxaborinane react regioselectively with olefins in the presence of RuHCl(CO)(PCy3)2 with the formation of functionalized vinylboron derivatives. The reaction opens a new catalytic route for preparation of organoboranes.

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