[3]Rotaxane synthesized via covalent bond formation can recognize cations forming a sandwich structure
Literature Information
Yoshinobu Nagawa, Jun-ichi Suga, Emiko Koyama, Masatoshi Kanesato
A novel [3]rotaxane composed of two 25-membered crownophanes and one axle molecule having two anthryl end groups was successfully synthesized via covalent bond formation followed by aminolysis, and can incorporate caesium ion into the space between the two macrocycles as a 1 ∶ 1 sandwich-type complex, whereas it makes a 1 ∶ 2 complex with lithium ion.
Related Literature
Time- and ensemble-averages in evolving systems: the case of Brownian particles in random potentials
Jörg Bewerunge, Florian Platten, Christoph Zunke, Andreas Heuer, Stefan U. Egelhaaf
DOI: 10.1039/C6CP02559E
Electrodeposition of Pt nanostructures with reproducible SERS activity and superhydrophobicity
Suhee Choi, Suji Kweon, Jongwon Kim
DOI: 10.1039/C5CP04261E
Design and synthesis of hollow NiCo2O4 nanoboxes as anodes for lithium-ion and sodium-ion batteries
DOI: 10.1039/C6CP02871C
Regioisomer-specific electron affinities and electronic structures of C70para-adducts at polar and equatorial positions with (bromo)benzyl radicals: photoelectron spectroscopy and theoretical study
Gao-Lei Hou, Lei-Jiao Li, Shu-Hui Li, Zhong-Ming Sun, Xiang Gao, Xue-Bin Wang
DOI: 10.1039/C6CP03978B
Interaction between ionic liquid cation and water: infrared predissociation study of [bmim]+·(H2O)n clusters
Jonathan M. Voss, Brett M. Marsh, Jia Zhou, Etienne Garand
DOI: 10.1039/C6CP02730J
Analyzing torquoselectivity in electrocyclic ring opening reactions of trans-3,4-dimethylcyclobutene and 3-formylcyclobutene through electronic structure principles
Alejandro Morales-Bayuelo, Sudip Pan, Julio Caballero, Pratim K. Chattaraj
DOI: 10.1039/C5CP02647D
IR spectroscopy of protonated leu-enkephalin and its 18-crown-6 complex embedded in helium droplets
Ana Isabel González Flórez, Doo-Sik Ahn, Sandy Gewinner, Wieland Schöllkopf, Gert von Helden
DOI: 10.1039/C5CP02172C
The Raman optical activity of β-d-xylose: where experiment and computation meet
François Zielinski, Shaun T. Mutter, Christian Johannessen, Ewan W. Blanch, Paul L. A. Popelier
DOI: 10.1039/C5CP02969D
Correction: Determination of Kamlet–Taft parameters for selected solvate ionic liquids
Baris Demir, Tiffany R. Walsh, Tom Welton
DOI: 10.1039/C6CP90177H
Predicting near-UV electronic circular dichroism in nucleosomal DNA by means of DFT response theory
Patrick Norman, Joseph Parello, Prasad L. Polavarapu, Mathieu Linares
DOI: 10.1039/C5CP02481A
You might also like
What precautions should be taken when handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3)?
When handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3), it ...
What precautions should be taken when handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9)?
When handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9), it...
How should waste containing 2-[2-(2-Methoxyethoxy)ethoxy]ethyl 4-methylbenzenesulfonate (CAS: 62921-74-8) be handled?
Waste containing this compound (CAS: 62921-74-8) should be handled according to ...
How should waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate be handled?
Waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate should be collected i...
How is 5-({4-[(2S,4R)-4-Hydroxy-2-methyltetrahydro-2H-pyran-4-yl]-2-thienyl}sulfanyl)-1-methyl-1,3-dihydro-2H-indol-2-one (CAS: 166882-70-8) typically synthesized?
This compound can be synthesized using a multi-step process involving the conjug...
Are there alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid (CAS: 7312-27-8) in synthesis?
There are several alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid in syn...
How should Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84-9) be stored?
Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84...
How should waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) be handled?
Waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) should be coll...
How is Methyl 5-iodo-2-methylbenzoate (CAS: 103440-54-6) typically synthesized?
Methyl 5-iodo-2-methylbenzoate can be synthesized through the iodination of meth...
How is 5-Chloro[1,2,4]triazolo[1,5-a]pyridine (CAS: 1427399-34-5) typically synthesized?
5-Chloro[1,2,4]triazolo[1,5-a]pyridine is commonly synthesized via the condensat...
Source Journal
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry











![1-Naphthalenesulfonic acid, 2-[(2-hydroxy-1-naphthalenyl)azo]-, bariumsalt (2:1) structure 1-Naphthalenesulfonic acid, 2-[(2-hydroxy-1-naphthalenyl)azo]-, bariumsalt (2:1) structure](https://static.chemtradehub.com/structs/110/1103-38-4-0b33.webp)


